Kopi luwak, also known as civet coffee, is the most expensive coffee in the world. The name "civet coffee" comes from the fact that the coffee berries are eaten by civets, which are mongoose-like critters, in Indonesia and the coffee beans are excreted by then after digestion. The beans are then cleaned and roasted to make the coffee.
A rare brew, this coffee is not available just everywhere, but Coffee & Tea LTD in Linden Hills, Minneapolis stocks it. The shop sells the coffee for $10 per 8-ounce cup, making it one of the most expensive cups of coffee in the country, if not the single most expensive. The owner, Jim Cone, buys green beans from Indonesia and roasts them to order in a vintage 1910 coffee roaster. He compares the coffee to fine wines, noting that it "might be too much to drink everyday" and describes the coffee as "having a rich and caramel-like taste."
Interestingly, Forbes has priced Kopi luwak at $160 per pound, while Coffee & Tea LTD sells it for $420 per pound. Granted, the coffee shop roasts its own beans on site, but it still seems like there would be a cheaper way to get your hands of a pound of the coffee than to pay retail there.
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